Reaction between ruthenium(0) complexes and dihalo compounds. A new method for the synthesis of ruthenium olefin metathesis catalysts

被引：136

作者：

Belderrain, TR ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH,ARNOLD & MABEL BECKMAN LABS CHEM SYNTHESIS,DIV CHEM & CHEM ENGN,PASADENA,CA 91125

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 18期

关键词：

D O I：

10.1021/om970514f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of ruthenium carbenes by the reaction of a Ru(0) compound or Ru(0) precursors with dihalo compounds is reported. A new procedure for the preparation of [Ru(H)(2)(H-2)(2)(PCy3)(2)] and the use of this complex as a starting material for the synthesis of ruthenium carbenes are presented.

引用

页码：4001 / 4003

页数：3