Two chiral coordination polymers: Preparation and X-ray structures of mono(4-sulfo-L-phenylalanine)(diaqua) zinc(II) and copper(II) complexes

被引：68

作者：

Xie, YR

Xiong, RG ^{[1
]}

Xue, X

Chen, XT

Xue, ZL

You, XZ

机构：

[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 12期

关键词：

D O I：

10.1021/ic010862g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal treatment of 4-sulfo-L-phenylalanine (H-2-SPA) with Zn(OH)(2) and Cu(OH)(2) affords two novel 1-D chiral coordination polymers [Zn(SPA)(H2O)(2)](2) (1) and [Cu(SPA)(H2O)(2)](n) (2) as chiral supramolecular aggregates through strong hydrogen bonding of the sulfonate group. 1 also displays a strong second harmonic generation (SHG) response.

引用

页码：3323 / +

页数：5

共 66 条

[1] A very large metallosupramolecular capsule with cube-like 43 topology assembled from twelve Cu(II) centers and eight tri-bidentate tri-anionic ligands derived from 2,4,6-triphenylazo-1,3,5-trihydroxybenzene [J].