Two chiral coordination polymers: Preparation and X-ray structures of mono(4-sulfo-L-phenylalanine)(diaqua) zinc(II) and copper(II) complexes

被引:68
作者
Xie, YR
Xiong, RG [1 ]
Xue, X
Chen, XT
Xue, ZL
You, XZ
机构
[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
关键词
D O I
10.1021/ic010862g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Hydrothermal treatment of 4-sulfo-L-phenylalanine (H-2-SPA) with Zn(OH)(2) and Cu(OH)(2) affords two novel 1-D chiral coordination polymers [Zn(SPA)(H2O)(2)](2) (1) and [Cu(SPA)(H2O)(2)](n) (2) as chiral supramolecular aggregates through strong hydrogen bonding of the sulfonate group. 1 also displays a strong second harmonic generation (SHG) response.
引用
收藏
页码:3323 / +
页数:5
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