Structure of shear-induced perforated layer phase in styrene-isoprene diblock copolymer melts

被引:64
作者
Ahn, JH
Zin, WC [1 ]
机构
[1] Pohang Univ Sci & Technol, Dept Mat Sci & Engn, Pohang 790784, Kyungbuk, South Korea
[2] Pohang Univ Sci & Technol, Polymer Res Inst, Pohang 790784, Kyungbuk, South Korea
关键词
D O I
10.1021/ma9912812
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The shear-induced hexagonally-perforated layer (HPL) structure of polystyrene-polyisoprene diblock copolymer melts was investigated by synchrotron small angle X-ray scattering. Results showed that the HPL structure was metastable and the oriented HPL transforms into the G phase with six-spot patterns. Scattering experiment indicated that the perforations were stacked in the ABCABC... patterns.
引用
收藏
页码:641 / 644
页数:4
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