In situ preparation of β-D-1-O-hydroxylamino carbohydrated polymers mediated by galactose oxidase

被引：23

作者：

Andreana, PR ^{[1
]}

Xie, WH ^{[1
]}

Cheng, HN ^{[1
]}

Qiao, L ^{[1
]}

Murphy, DJ ^{[1
]}

Gu, QM ^{[1
]}

Wang, PG ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 11期

关键词：

D O I：

10.1021/ol0258379

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Galactose oxidase produced a C-6 aldehyde in various terminal-containing galactose hydroxylamines for the simultaneous in situ generation of an A-B type condensation for the construction of unique oxime polymers. Molecular weights of the corresponding polymers were determined to be in the range of 4200-8900 g/mol, respectively. This indicates that approximately 20-25 sugar units were incorporated in these unique polymers.

引用

页码：1863 / 1866

页数：4

共 43 条

[1]

ANDREANA PR, 2001, IN PRESS SYNTHESIS M

[2]

[Anonymous], 1997, POLYM MAT SCI ENG PR

[3]

AVIGAD G, 1962, J BIOL CHEM, V237, P2736

[4] STEREOSELECTIVE PHASE-TRANSFER-CATALYZED SYNTHESES OF GLYCOSYLOXYSUCCINIMIDES AND THEIR TRANSFORMATIONS INTO GLYCOPROBES [J].