Hydrogen bonds seal single-molecule capsules

被引：104

作者：

Atwood, JL ^{[1
]}

Szumna, A ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 36期

关键词：

D O I：

10.1021/ja027191l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of methanol the tetrakis(benzoxazines) complex tetramethylammonium cation within the cavity, and the cavity is completely sealed by two intramolecular hydrogen bonds between amide groups. The Cl- anion is found external to the cavity. In CHCl3, Me4N+ is complexed within the cavity, but the Cl- anion acts as a stopper in the upper rim of the cavity, hydrogen-bonded to the amide groups. The solution results are supported by single-crystal X-ray structural studies of both the single-molecule molecular capsules, and those stoppered by Cl-. Copyright © 2002 American Chemical Society.

引用

页码：10646 / 10647

页数：2

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