Preparation of porous poly(dimethylsiloxane)-based honeycomb materials with hierarchal surface features and their use as soft-lithography templates

被引：137

作者：

Connal, Luke A. ^{[1
]}

Qiao, Greg G. ^{[1
]}

机构：

[1] Univ Melbourne, Dept Chem & Biomol Engn, Polymer Sci Grp, Parkville, Vic 3010, Australia

来源：

ADVANCED MATERIALS | 2006年 / 18卷 / 22期

关键词：

D O I：

10.1002/adma.200600982

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ordered hierarchal porous materials made via the "breath figure" technique are prepared from solutions of poly(dimethylsiloxane) -based star polymers. The successful formation of regular porous materials on ordered nonflat substrates (see figure and inside cover) is described. The materials are used as soft lithography masters to produce a variety of exotic structures. Potential applications of the technique includes the preparation of substrates for cellular growth or photonic materials.

引用

页码：3024 / +

页数：6

共 40 条

[1] Studies on microgels. 5. Synthesis of microgels via living free radical polymerisation [J].

Abrol, S ;

Caulfield, MJ ;

Qiao, GG ;

Solomon, DH .

POLYMER, 2001, 42 (14) :5987-5991

[2] Studies on microgels .3. Synthesis using living free radical polymerization [J].

Abrol, S ;

Kambouris, PA ;

Looney, MG ;

Solomon, DH .

MACROMOLECULAR RAPID COMMUNICATIONS, 1997, 18 (09) :755-760

[3] Breath figures [J].

Falkirk, A .

NATURE, 1911, 86 :516-517

[4] Star-shaped polymers by metal-catalyzed living radical polymerization. 1. Design of Ru(II)-based systems and divinyl linking agents [J].

Baek, KY ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 2001, 34 (02) :215-221

[5] Defect-free nanoporous thin films from ABC triblock copolymers [J].

Bang, Joona ;

Kim, Seung Hyun ;

Drockenmuller, Eric ;

Misner, Matthew J. ;

Russell, Thomas P. ;

Hawker, Craig J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) :7622-7629

[6] A modular approach toward functionalized three-dimensional macromolecules:: From synthetic concepts to practical applications [J].

Bosman, AW ;

Vestberg, R ;

Heumann, A ;

Fréchet, JMJ ;

Hawker, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (03) :715-728

[7] Breath figures as a dynamic templating method for polymers and nanomaterials [J].

Bunz, UHF .

ADVANCED MATERIALS, 2006, 18 (08) :973-989

[8] Porous polymer films and honeycomb structures based on amphiphilic dendronized block copolymers [J].

Cheng, CX ;

Tian, Y ;

Shi, YQ ;

Tang, RP ;

Xi, F .

LANGMUIR, 2005, 21 (14) :6576-6581

[9] From well defined star-microgels to highly ordered honeycomb films [J].

Connal, LA ;

Gurr, PA ;

Qiao, GG ;

Solomon, DH .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (12) :1286-1292

[10]

de Boer B, 2000, ADV MATER, V12, P1581, DOI 10.1002/1521-4095(200011)12:21<1581::AID-ADMA1581>3.0.CO

← 1 2 3 4 →