Solid-state preparation of hybrid organometallic-organic macrocyclic adducts with long chain dicarboxylic acids

被引：27

作者：

Braga, Dario ^{[1
]}

Giaffreda, Stefano Luca ^{[1
]}

Grepioni, Fabrizia ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 37期

关键词：

D O I：

10.1039/b608691h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The supramolecular macrocyclic adducts of general formula {[Fe(eta(5)-C5H4-C5H4N)(2)]center dot[HOOC(CH2)(n)COOH]}(2) with n = 4 (adipic acid), n = 6 (suberic acid), n = 7 (azelaic acid) and n = 8 (sebacic acid) have been obtained quantitatively by kneading powdered samples of the crystalline organometallic and organic reactants with drops of MeOH(for n = 4, 6 and 7) and by direct crystallization from MeOH for n = 8, while the adduct with n = 5 represents an isomeric open chain alternative to the macrocycle.

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收藏

页码：3877 / 3879

页数：3

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