H2 or O2 evolution from aqueous solutions on layered oxide photocatalysts consisting of Bi3+ with 6s2 configuration and d0 transition metal ions

被引：513

作者：

Kudo, A ^{[1
]}

Hijii, S ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 10期

关键词：

D O I：

10.1246/cl.1999.1103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bi2W2O9, Bi2WO6, and Bi3TiNbO9 consisting of layered structure with perovskite slabs interleaved with Bi2O2 layers showed photocatalytic activities for H-2 evolution from an aqueous methanol solution and O-2 evolution from an aqueous silver nitrate solution. Bi2WO6 with the Aurivillius structure and a 2.8 eV band gap was active for the O-2 evolution reaction under visible light irradiation (lambda>420 nm).

引用

页码：1103 / 1104

页数：2

共 20 条

[1] NEW LAYERED STRUCTURE OF BI2W2O9 DETERMINED BY 1 MV HIGH-RESOLUTION ELECTRON-MICROSCOPY [J].

BANDO, Y ;

WATANABE, A ;

SEKIKAWA, Y ;

GOTO, M ;

HORIUCHI, S .

ACTA CRYSTALLOGRAPHICA SECTION A, 1979, 35 (JAN) :142-145

[2] Oxide ion conductivity in Bi(2)W(1-x)ME(x)O(6-x/2) (ME=Nb,Ta) [J].

Baux, N ;

Vannier, RN ;

Mairesse, G ;

Nowogrocki, G .

SOLID STATE IONICS, 1996, 91 (3-4) :243-248

[3]

Bordun OM, 1998, INORG MATER+, V34, P1270

[4] ELECTRICAL AND OPTICAL PROPERTIES OF FERROELECTRIC BI4TI3O12 SINGLE CRYSTALS [J].

CUMMINS, SE ;

CROSS, LE .

JOURNAL OF APPLIED PHYSICS, 1968, 39 (05) :2268-&

[5] PHOTOOXIDATION OF WATER SENSITIZED BY WO3 POWDER [J].

DARWENT, JR ;

MILLS, A .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1982, 78 :359-367

[6] ION-EXCHANGEABLE LAYERED NIOBATES AS PHOTOCATALYSTS [J].

DOMEN, K ;

EBINA, Y ;

SEKINE, T ;

TANAKA, A ;

KONDO, J ;

HIROSE, C .

CATALYSIS TODAY, 1993, 16 (3-4) :479-486

[7] THE CRYSTAL-CHEMISTRY AND DIELECTRIC-PROPERTIES OF THE AURIVILLIUS FAMILY OF COMPLEX BISMUTH OXIDES WITH PEROVSKITE-LIKE LAYERED STRUCTURES [J].

FRIT, B ;

MERCURIO, JP .

JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 188 (1-2) :27-35

[8] Microstructure and dielectric properties of epitaxial Bi2WO6 deposited by pulsed laser ablation [J].

Hamada, M ;

Tabata, H ;

Kawai, T .

THIN SOLID FILMS, 1997, 306 (01) :6-9

[9] THERMAL ANOMALIES IN BI2WO6 AND EPR OF DOPED GD-3+ IONS [J].

HIROSE, T ;

KAWAMINAMI, M ;

OBARA, K ;

ARAKAWA, M ;

TAKEUCHI, H .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1993, 62 (05) :1758-1766

[10] ELECTRON-MICROSCOPY OF FERROELECTRIC BISMUTH OXIDES CONTAINING PEROVSKITE LAYERS [J].

HUTCHISON, JL ;

ANDERSON, JS ;

RAO, CNR .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1977, 355 (1682) :301-312

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