Lewis acid behavior of cationic complexes of palladium(II) and platinum(II): some examples of catalytic applications

被引：44

作者：

Strukul, G ^{[1
]}

机构：

[1] Univ Venice, Dept Chem, I-30123 Venice, Italy

来源：

TOPICS IN CATALYSIS | 2002年 / 19卷 / 01期

关键词：

oxidation; acetalization; Diels-Alder; palladium(II); platinum(II);

D O I：

10.1023/A:1013877131474

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The behavior of a variety of cationic diphosphine complexes of Pd(II) and Pt(II) as Lewis acid catalysts is reviewed. The reactions considered are the Baeyer-Villiger oxidation of ketones, the acetalization of aldehydes and ketones and the Diels-Alder reaction in both their regular and enantioselective version.

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页码：33 / 42

页数：10

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