Photo-crosslinking polymers by fullerene

被引：15

作者：

Tajima, Y ^{[1
]}

Tezuka, Y ^{[1
]}

Yajima, H ^{[1
]}

Ishii, T ^{[1
]}

Takeuchi, K ^{[1
]}

机构：

[1] RIKEN,INST PHYS & CHEM RES,WAKO,SAITAMA 35101,JAPAN

来源：

POLYMER | 1997年 / 38卷 / 20期

关键词：

photo-crosslinking; fullerene; furan derivative;

D O I：

10.1016/S0032-3861(97)00191-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Photochemical addition of furan derivatives to fullerene C-60 was applied to the photo-crosslinking of polymers with C-60 A polymer having furan units in the side chains was synthesized by the reaction of poly(2-hydroxyethylmethacrylate) with 2-furoic chloride. A 1,1,2,2-tetrachloroethane solution of the polymer was exposed to visible light in the presence of C-60 The solution turned to a gel after 10 h and then solidified completely. The photo-crosslinking process was monitored in situ by dynamic viscoelasticity measurement. (C) 1997 Elsevier Science Ltd.

引用

页码：5255 / 5257

页数：3

共 17 条

[11] [3+2] AND [4+2] CYCLOADDITIONS OF C60 [J].