Chemically grafted field effect transistors for the detection of potassium ions

被引:9
作者
Elbhiri, Z
Chovelon, JM
Jaffrezic-Renault, N
Chevalier, Y
机构
[1] Ecole Cent Lyon, IFoS PCI, F-69131 Ecully, France
[2] CNRS, LMOPS, F-69390 Vernaison, France
来源
SENSORS AND ACTUATORS B-CHEMICAL | 1999年 / 58卷 / 1-3期
关键词
field effect transistors; grafting; crown ether;
D O I
10.1016/S0925-4005(99)00109-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
K+-ISFETs are prepared by grafting, on the silica gate insulator surface, silylated crown-ether molecules which were synthesized for the first time. Three grafting reactions were tested. The responses of the grafted ISFETs are sub-nernstian. They are analyzed through the modified site-binding model and the density of grafted sites was found to be equal to 6 X 10(12) cm(-2) with the chloro-silylated molecule and 13 x 10(12) cm(-2) with the dimethylamino-silylated molecule, the complexation constant of K+ ions being found to be equal to 10(2.1). (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:491 / 496
页数:6
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