STM Insight into Hydrogen-Bonded Bicomponent 1D Supramolecular Polymers with Controlled Geometries at the Liquid-Solid Interface

被引：61

作者：

Ciesielski, Artur ^{[1
]}

Schaeffer, Gael ^{[1
]}

Petitjean, Anne ^{[1
]}

Lehn, Jean-Marie ^{[1
]}

Samori, Paolo ^{[1
]}

机构：

[1] Univ Strasbourg, ISIS, CNRS, UMR 7006, F-67000 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 11期

关键词：

interfaces; polymers; scanning probe microscopy; self-assembly; supramolecular chemistry; MOLECULAR-RECOGNITION; DERIVATIVES; ASSEMBLIES; CHEMISTRY; PATTERNS;

D O I：

10.1002/anie.200805680

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Bicomponent supramolecular polymers, consisting of two alternating molecules bridged through six H-bonds, are observed by STM at the solid-liquid interface. Control of the geometry of the 1D architecture was obtained by using two different connecting molecules with different conformational rigidity, affording either linear (see picture, left) or zigzag (right) motifs. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2039 / 2043

页数：5

共 47 条

[41] Supramolecular Crystal Engineering at the Solid-Liquid interface from First Principles: Toward Unraveling the Thermodynamics of 2D Self-Assembly [J].