2,2′-isopropylidenebis[(4R)-(1-adamantyl)-2-oxazoline] (Adam-Box).: A new enantiopure C2-symmetrical ligand:: enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations

被引：33

作者：

Clariana, J ^{[1
]}

Comelles, J ^{[1
]}

Moreno-Mañas, M ^{[1
]}

Vallribera, A ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Chem, Barcelona 08193, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 14期

关键词：

D O I：

10.1016/S0957-4166(02)00404-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title bisoxazoline (Box) featuring two adamantane skeletons (Adam-Box) is a ligand of (R,R)-configuration, which combined with copper sources makes excellent catalysts for enantioselective cyclopropanations, Diels-Alder reactions, and allylic oxidations. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：1551 / 1554

页数：4

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