Metal complexes of a tetraazacyclotetradecane bearing highly fluorinated tails: New catalysts for the oxidation of hydrocarbons under fluorous biphasic conditions

被引：70

作者：

Pozzi, G

Cavazzini, M

Quici, S

Fontana, S

机构：

[1] UNIV MILAN,CTR CNR,I-20133 MILAN,ITALY

[2] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

[3] AUSIMONT SPA,CTR RIC BOLLATE,I-20021 BOLLATE,MI,ITALY

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(97)01805-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The commercially available macrocycle tetraazacyclotetradecane (cyclam) has been converted into the fluorocarbon soluble ligand 1 by N-functionalization with RFCH2OCH2CH2OTs 3, wherein RF is a (per)fluorooxyalkylenic chain. Upon complexation with 1, transition metal salts can be selectively solubilized in fluorocarbons thus providing new catalysts for the oxidative functionalization of hydrocarbons under fluorous biphasic (FB) conditions. (C) 1997 Elsevier Science Ltd.

引用

页码：7605 / 7608

页数：4

共 19 条

[1]

[Anonymous], [No title captured], Patent No. 5463082

[2]

[Anonymous], ORGANOFLUORINE CHEM

[3]

BATTIONI F, 1996, CHEM COMMUN, P2036

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