Absolute configuration of an intermediate in the asymmetric synthesis of natural beta-hydroxy and beta-amino acids

被引：1

作者：

Carballo, R

FernandezSuarez, M

Munoz, L

Riguera, R

MaichleMossmer, C

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM ORGAN,E-15706 SANTIAGO COMPOSTE,SPAIN

[2] UNIV TUBINGEN,INST ANORGAN CHEM,D-72076 TUBINGEN,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270197005957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The single-crystal X-ray structure determination of enantiomerically pure (4R,5S)-3-[(2R,3S)-3-hydroxy-2-methyl-7-octynoyl] -4-methyl-5-phenyl-1,3-oxazolidin-2-one, C19H23NO4, at 223 K is reported. The absolute configuration of this molecule has been determined.

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页码：1312 / 1314

页数：3

相关论文

共 12 条

[1]

Enraf-Nonius, 1989, CAD 4 SOFTW VERS 5 0

[2] ENANTIOSELECTIVE ALDOL CONDENSATIONS .2. ERYTHRO-SELECTIVE CHIRAL ALOL CONDENSATIONS VIA BORON ENOLATES [J].

EVANS, DA ;

BARTROLI, J ;

SHIH, TL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (08) :2127-2129

[3] Onchidin B: A new cyclodepsipeptide from the mollusc Onchidium sp [J].

Fernandez, R ;

Rodriguez, J ;

Quinoa, E ;

Riguera, R ;

Munoz, L ;

FernandezSuarez, M ;

Debitus, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (46) :11635-11643

[4] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[5]

FRENZ BA, 1983, ENRAF NONIUS STRUCTU

[6]

GAGE JR, 1989, ORG SYNTH, V68, P77

[7] A CHIRAL N-CROTONYLOXAZOLIDINONE DIELS-ALDER ADDUCT [J].

MARSH, RE ;

SCHAEFER, WP ;

KUKKOLA, PJ ;

MYERS, AG .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1622-1624

[8] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

[9] ONCHIDIN - A CYTOTOXIC DEPSIPEPTIDE WITH C-2 SYMMETRY FROM MARINE MOLLUSK [J].

RODRIGUEZ, J ;

FERNANDEZ, R ;

QUINOA, E ;

RIGUERA, R ;

DEBITUS, C ;

BOUCHET, P .

TETRAHEDRON LETTERS, 1994, 35 (49) :9239-9242

[10] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473