Organometallic halides: Preparation and physical and chemical properties of tris[(eta-pentamethylcyclopentadienyl)dichlorovanadium], [(eta-C5Me5)V(mu-Cl)(2)](3)

被引：24

作者：

Abernethy, CD

Bottomley, F

Decken, A

Thompson, RC

机构：

[1] UNIV NEW BRUNSWICK,DEPT CHEM,FREDERICTON,NB E3B 5A3,CANADA

[2] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER,BC V6T 1Y6,CANADA

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 09期

关键词：

D O I：

10.1021/om960482g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster [(eta-C5Me5)V(mu-Cl)(2)](3) was synthesized from VCl3(thf)(3) and (Bu3SnC5Me5)-Sn-n. It was oxidized by O-2 to give (eta-C5Me5)VCl2(O), and by NaN3 to give [(eta-C5Me5)VCl(mu-N)](2). X-ray diffraction showed that [(eta-C5Me5)V(mu-Cl)(2)](3) had an equilateral triangle of vanadium atoms (mean V-V 3.367 (2) Angstrom), with each edge of the triangle symmetrically bridged by two chlorine atoms. The cluster contains six core electrons. The cluster [(eta-C5Me5)V(mu-Cl-2](3) had a magnetic moment of 2.92 mu(B) at room temperature and showed antiferromagnetic behavior.

引用

页码：1865 / 1869

页数：5

共 60 条

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