Splitting of the nonlinear temperature dependence of selection processes into the temperature dependencies of the single reaction pathways

被引：4

作者：

Heller, D ^{[1
]}

Buschmann, H ^{[1
]}

Neumann, H ^{[1
]}

机构：

[1] GRUNENTHAL GMBH,FORSCHUNGSZENTRUM,D-52078 AACHEN,GERMANY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 125卷 / 01期

关键词：

nonlinear temperature dependence; selection process;

D O I：

10.1016/S1381-1169(97)00061-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The paper describes a concept, which allows the determination of the temperature dependencies of the single reaction pathways in a selection process based on brutto-activity and selectivity measurements. (C) 1997 Elsevier Science B.V.

引用

页码：9 / 13

页数：5

共 17 条

[1] LIGAND-ACCELERATED CATALYSIS [J].

BERRISFORD, DJ ;

BOLM, C ;

SHARPLESS, KB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (10) :1059-1070

[2] KINETIC COUPLING IN AND BETWEEN CATALYTIC CYCLES [J].

BOUDART, M ;

DJEGAMARIADASSOU, G .

CATALYSIS LETTERS, 1994, 29 (1-2) :7-13

[3] CHIRAL INDUCTION IN PHOTOCHEMICAL-REACTIONS .10. THE PRINCIPLE OF ISOINVERSION - A MODEL OF STEREOSELECTION DEVELOPED FROM THE DIASTEREOSELECTIVITY OF THE PATERNO-BUCHI REACTION [J].

BUSCHMANN, H ;

SCHARF, HD ;

HOFFMANN, N ;

PLATH, MW ;

RUNSINK, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) :5367-5373

[4] THE ISOINVERSION PRINCIPLE - A GENERAL-MODEL OF CHEMICAL SELECTIVITY [J].

BUSCHMANN, H ;

SCHARF, HD ;

HOFFMANN, N ;

ESSER, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1991, 30 (05) :477-515

[5] A critical analysis of the mechanistic basis of enantioselectivity in the bis-cinchona alkaloid catalyzed dihydroxylation of olefins [J].

Corey, EJ ;

Noe, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (45) :11038-11053

[6] Theory does not support an osmaoxetane intermediate in the osmium-catalyzed dihydroxylation of olefins [J].

Dapprich, S ;

Ujaque, G ;

Maseras, F ;

Lledos, A ;

Musaev, DG ;

Morokuma, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (46) :11660-11661

[7] TEMPERATURE EFFECTS IN ASYMMETRIC DIHYDROXYLATION - EVIDENCE FOR A STEPWISE MECHANISM [J].

GOBEL, T ;

SHARPLESS, KB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (09) :1329-1331

[8] A REASSESSMENT OF THE ISOINVERSION RELATIONSHIP [J].

HALE, KJ ;

RIDD, HJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (08) :1601-1605

[9] A REASSESSMENT OF THE ISOINVERSION PRINCIPLE [J].

HALE, KJ ;

RIDD, JH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (03) :357-358

[10] Nonlinear temperature behavior of product ratios in selection processes [J].

Heller, D ;

Buschmann, H ;

Scharf, HD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (16) :1852-1854

← 1 2 →