Cotton-Textile-Enabled, Flexible Lithium-Ion Batteries with Enhanced Capacity and Extended Lifespan

被引:203
作者
Gao, Zan [1 ]
Song, Ningning [1 ]
Zhang, Yunya [1 ]
Li, Xiaodong [1 ]
机构
[1] Univ Virginia, Dept Mech & Aerosp Engn, Charlottesville, VA 22904 USA
基金
美国国家科学基金会;
关键词
lithium-ion battery; nickel sulfide; graphene; nanostructure; flexible power source; ANODE MATERIALS; ENERGY-STORAGE; GRAPHENE; PERFORMANCE; NANOCOMPOSITES; COMPOSITES; NI3S2; NANOSTRUCTURES; NANOPARTICLES; NANOCRYSTALS;
D O I
10.1021/acs.nanolett.5b03698
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Activated cotton textile (ACT) with porous tubular fibers embedded with NiS2 nanobowls and wrapped with conductive graphene sheets (ACT/NiS2-graphene) was fabricated by a simple two-step heat treatment method. When used as a binder-free electrode, the ACT/NiS2-graphene electrode exhibited an exceptional electrochemical performance including ultrahigh initial discharge capacity (-4710 mAh g(-1) at 0.01 degrees C), magnificent rate performance (the discharge capacitance retained at -,645 mAh g(-1) at 1 degrees C after 100 cycles) and excellent cyclic stability (the discharge capacitance recovered to,-1016 mAh g(-1) at 0.1 degrees C after 400 cycles).
引用
收藏
页码:8194 / 8203
页数:10
相关论文
共 69 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   Towards Textile Energy Storage from Cotton T-Shirts [J].
Bao, Lihong ;
Li, Xiaodong .
ADVANCED MATERIALS, 2012, 24 (24) :3246-3252
[3]   Li-O2 and Li-S batteries with high energy storage (vol 11, pg 19, 2012) [J].
Bruce, Peter G. ;
Freunberger, Stefan A. ;
Hardwick, Laurence J. ;
Tarascon, Jean-Marie .
NATURE MATERIALS, 2012, 11 (02)
[4]   One-pot synthesis of flowerlike Ni7S6 and its application in selective hydrogenation of chloronitrobenzene [J].
Cao, Feng ;
Liu, Ruixia ;
Zhou, Liang ;
Song, ShuYan ;
Lei, YongQian ;
Shi, WeiDong ;
Zhao, Fengyu ;
Zhang, Hongjie .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (06) :1078-1085
[5]   Building a Better Battery [J].
Chiang, Yet-Ming .
SCIENCE, 2010, 330 (6010) :1485-1486
[6]   Synthesis of nanostructured Ni3S2 with different morphologies as negative electrode materials for lithium ion batteries [J].
Duan, Wenchao ;
Yan, Wenchao ;
Yan, Xiao ;
Munakata, Hirokazu ;
Jin, Yongcheng ;
Kanamura, Kiyoshi .
JOURNAL OF POWER SOURCES, 2015, 293 :706-711
[7]   Ionic Liquid Enabled FeS2 for High-Energy-Density Lithium-Ion Batteries [J].
Evans, Tyler ;
Piper, Daniela Molina ;
Kim, Seul Cham ;
Han, Sang Sub ;
Bhat, Vinay ;
Oh, Kyu Hwan ;
Lee, Se-Hee .
ADVANCED MATERIALS, 2014, 26 (43) :7386-7392
[8]   Interpretation of Raman spectra of disordered and amorphous carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107
[9]  
Ford ENJ, 2010, J ENG FIBER FABR, V5, P10
[10]   Microstructural design of hybrid CoO@NiO and graphene nano-architectures for flexible high performance supercapacitors [J].
Gao, Zan ;
Song, Ningning ;
Li, Xiaodong .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (28) :14833-14844