Atomic layer deposition of ZrO2/La2O3 high-k dielectrics on germanium reaching 0.5 nm equivalent oxide thickness

被引:36
作者
Abermann, S. [1 ]
Bethge, O. [1 ]
Henkel, C. [1 ]
Bertagnolli, E. [1 ]
机构
[1] Vienna Univ Technol, Inst Solid State Elect, A-1040 Vienna, Austria
基金
奥地利科学基金会;
关键词
atomic layer deposition; current density; elemental semiconductors; germanium; high-k dielectric thin films; lanthanum compounds; MOS capacitors; permittivity; zirconium compounds; GROWTH; FILMS;
D O I
10.1063/1.3173199
中图分类号
O59 [应用物理学];
学科分类号
摘要
We investigate ultrathin ZrO2/La2O3 high-k dielectric stacks on germanium grown by atomic layer deposition. La2O3 is deposited from tris(N,N-'-diisopropylformamidinate)-lanthanum and oxygen. Interfacial layer-free oxide stacks with a relative dielectric constant of 21 and equivalent oxide thickness values as low as 0.5 nm are obtained. Metal oxide semiconductor capacitors with platinum as the gate electrode exhibit well-behaved capacitance-voltage characteristics, gate leakage current densities in the range of 0.01-1 A/cm(2), and interface trap densities in the range of similar to 3x10(12) eV(-1) cm(-2).
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页数:3
相关论文
共 31 条
[1]   Lanthanum-Zirconate and Lanthanum-Aluminate Based High-κ Dielectric Stacks on Silicon Substrates [J].
Abermann, S. ;
Henkel, C. ;
Bethge, O. ;
Straif, C. J. ;
Hutter, H. ;
Bertagnolli, E. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (05) :G53-G57
[2]  
[Anonymous], P CHAR METR ULSI
[3]   Nanoscale germanium MOS dielectrics -: Part II:: High-κ gate dielectrics [J].
Chui, Chi On ;
Kim, Hyoungsub ;
Chi, David ;
McIntyre, Paul C. ;
Saraswat, Krishna C. .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2006, 53 (07) :1509-1516
[4]   Atomic layer deposition of high-κ dielectric for germanium MOS applications-substrate surface preparation [J].
Chui, CO ;
Kim, H ;
McIntyre, PC ;
Saraswat, KC .
IEEE ELECTRON DEVICE LETTERS, 2004, 25 (05) :274-276
[5]  
Chui CO, 2002, INTERNATIONAL ELECTRON DEVICES 2002 MEETING, TECHNICAL DIGEST, P437, DOI 10.1109/IEDM.2002.1175872
[6]   An X-ray photoelectron spectroscopy study of the HF etching of native oxides on Ge(111) and Ge(100) surfaces [J].
Deegan, T ;
Hughes, G .
APPLIED SURFACE SCIENCE, 1998, 123 :66-70
[7]   Interface engineering for Ge metal-oxide-semiconductor devices [J].
Dimoulas, A. ;
Brunco, D. P. ;
Ferrari, S. ;
Seo, J. W. ;
Panayiotatos, Y. ;
Sotiropoulos, A. ;
Conard, T. ;
Caymax, M. ;
Spiga, S. ;
Fanciulli, M. ;
Dieker, Ch. ;
Evangelou, E. K. ;
Galata, S. ;
Houssa, M. ;
Heyns, M. M. .
THIN SOLID FILMS, 2007, 515 (16) :6337-6343
[8]   Deposition of lanthanum zirconium oxide high-κ films by liquid injection atomic layer deposition [J].
Gaskell, J. M. ;
Jones, A. C. ;
Aspinall, H. C. ;
Taylor, S. ;
Taechakumput, P. ;
Chalker, P. R. ;
Heys, P. N. ;
Odedra, R. .
APPLIED PHYSICS LETTERS, 2007, 91 (11)
[9]   Surface chemistry for atomic layer growth [J].
George, SM ;
Ott, AW ;
Klaus, JW .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13121-13131
[10]   Nucleation and growth of atomic layer deposited HfO2 gate dielectric layers on chemical oxide (Si-O-H) and thermal oxide (SiO2 or Si-O-N) underlayers [J].
Green, ML ;
Ho, MY ;
Busch, B ;
Wilk, GD ;
Sorsch, T ;
Conard, T ;
Brijs, B ;
Vandervorst, W ;
Räisänen, PI ;
Muller, D ;
Bude, M ;
Grazul, J .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (12) :7168-7174