Three-dimensional, two-phase, CFD model for the design of a direct methanol fuel cell

被引:38
作者
Danilov, Valeri A.
Lim, Jongkoo
Moon, Il
Chang, Hyuk
机构
[1] Yonsei Univ, Dept Chem Engn, Seoul 120749, South Korea
[2] Samsung Adv Inst Technol, Suwon 400600, South Korea
关键词
direct methanol fuel cell; two-phase model; gas management; flow-field design; computational fluid dynamics; PROTON-EXCHANGE MEMBRANE; NUMERICAL-SIMULATION; GAS EVOLUTION; MASS-TRANSFER; FLOW;
D O I
10.1016/j.jpowsour.2006.07.071
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study presents a computational fluid dynamics.(CFD) model for modelling gas evolution and current distribution in a direct methanol fuel cell (DMFC). The improved two-phase model includes a new sub-model for estimating the interface mass transfer without empirical correlations. Simulation results in a horizontal channel of the DMFC agree with typical trends reported in the literature for bubbly flows. The increase in inlet flow rate is found to lead to a decrease in the gas content in the outlet of the anode channels. A case study illustrates applications of the CFD model for modelling gas evolution and current distribution in a DMFC with a parallel flow-field design. Simulation results with a improved two-phase model provide an explanation of experimental observations of a transparent DMFC with parallel channels. An improved three-dimensional CFD model includes all relevant phenomena and is valuable for gas management in a DMFC design. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:992 / 1002
页数:11
相关论文
共 26 条
[11]  
Geiger A, 2000, SCI REPORT, VV, P86
[12]   SIMULATION OF FLOW AND MASS-TRANSFER IN TAYLOR FLOW THROUGH A CAPILLARY [J].
IRANDOUST, S ;
ANDERSSON, B .
COMPUTERS & CHEMICAL ENGINEERING, 1989, 13 (4-5) :519-526
[13]   Two-dimensional simulation of direct methanol fuel cell - A new (embedded) type of current collector [J].
Kulikovsky, AA ;
Divisek, J ;
Kornyshev, AA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (03) :953-959
[14]   Electrochemical and flow characterization of a direct methanol fuel cell [J].
Lu, GQ ;
Wang, CY .
JOURNAL OF POWER SOURCES, 2004, 134 (01) :33-40
[15]  
MUGIA G, 2003, J ELECTROCHEM SOC, V150, pA1231
[16]   Computational model of a PEM fuel cell with serpentine gas flow channels [J].
Nguyen, PT ;
Berning, T ;
Djilali, N .
JOURNAL OF POWER SOURCES, 2004, 130 (1-2) :149-157
[17]   Rigorous dynamic model of a direct methanol fuel cell based on Maxwell-Stefan mass transport equations and a Flory-Huggins activity model: Formulation and experimental validation [J].
Schultz, T ;
Sundmacher, KS .
JOURNAL OF POWER SOURCES, 2005, 145 (02) :435-462
[18]   Electrochemical and gas evolution characteristics of direct methanol fuel cells with stainless steel mesh flow beds [J].
Scott, K ;
Argyropoulos, P ;
Yiannopoulos, P ;
Taama, WM .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (08) :823-832
[19]   A current distribution model of a porous fuel cell electrode [J].
Scott, K ;
Argyropoulos, P .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 567 (01) :103-109
[20]   CFD-based modelling of proton exchange membrane fuel cells [J].
Sivertsen, BR ;
Djilali, N .
JOURNAL OF POWER SOURCES, 2005, 141 (01) :65-78