Two new complexes of phenylboronic acid with N-salicylidene-4-aminobutanol

被引：28

作者：

Barba, V ^{[1
]}

Cuahutle, D ^{[1
]}

Ochoa, ME ^{[1
]}

Santillan, R ^{[1
]}

Farfán, N ^{[1
]}

机构：

[1] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico

来源：

INORGANICA CHIMICA ACTA | 2000年 / 303卷 / 01期

关键词：

crystal structures; boronate complexes; tridentate ligand complexes;

D O I：

10.1016/S0020-1693(99)00477-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tridentate ligand N-salicylidene-4-aminobutanol (6) was obtained by condensation of salicylaldehyde with 4-aminobutanol and reacted with phenylboronic acid to afford either the dimeric structure, bis[mu-[2-[[(4-hydroxy-kappa O)butyl]imino-kappa N]methyl-pheno-lato(2-)-kappa O]]diphenyldiboro (7) or the monomeric derivative, 2-phenylbenzo[j]-8-aza-1,3-dioxa-2-boracycloundeca-8-ene (8), depending on the reaction conditions. The monomeric structure is a [5.4.0] heterobicycle boronate and has been analyzed by X-ray crystallography. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：7 / 11

页数：5

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