Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the 'Chinese lantern' structure

被引：16

作者：

Amel'chenkova, EV ^{[1
]}

Denisova, TO ^{[1
]}

Nefedov, SE ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2004年 / 14卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1070/MC2004v014n03ABEH001918

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The treatment of the product of a thermal reaction of manganese(H) acetate tetrahydrate and trimethylacetic acid with triethylamine under reflux results in the unusual complex Mn-3(mu,eta(2)-OOCBut)(4)(mu-OOCBut)(2)[OC(Bu-t)OHNEt3](2), which, according to X-ray diffraction analysis, incorporates a linear Mn3 metal skeleton and four chelate-bridging trimethylacetate anions; a similar reaction at room temperature yields the Mn-2(mu-OOCBut)(4)[OC(Bu-t)OHNEt3](2) complex, which has a 'Chinese lantern' structure with the (MnMn)-Mn-... distance equal to 3.1087(8) Angstrom.

引用

页码：103 / 104

页数：2

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