Dynamical heterogeneities in a supercooled Lennard-Jones liquid

被引:888
作者
Kob, W
Donati, C
Plimpton, SJ
Poole, PH
Glotzer, SC
机构
[1] NATL INST STAND & TECHNOL, CTR THEORET & COMPUTAT MAT SCI, GAITHERSBURG, MD 20899 USA
[2] NATL INST STAND & TECHNOL, DIV POLYMERS, GAITHERSBURG, MD 20899 USA
[3] SANDIA NATL LABS, PARALLEL COMPUTAT SCI DEPT, ALBUQUERQUE, NM 87185 USA
[4] UNIV WESTERN ONTARIO, DEPT APPL MATH, LONDON, ON N6A 5B7, CANADA
关键词
D O I
10.1103/PhysRevLett.79.2827
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present the results of a molecular dynamics computer simulation study in which we investigate whether a supercooled Lennard-Jones liquid exhibits dynamical heterogeneities. We evaluate the non-Gaussian parameter for the self part of the van Hove correlation function and use it to identify ''mobile'' particles. We find that these particles form clusters whose sizes grow with decreasing temperature. We also find that the relaxation time of the mobile particles is significantly shorter than that of the average particle, and that this difference increases with decreasing temperature.
引用
收藏
页码:2827 / 2830
页数:4
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