Iron(III) spin crossover compounds

被引：165

作者：

van Koningsbruggen, PJ

Maeda, Y

Oshio, H

机构：

[1] Univ Groningen, Statingh Inst Chem & Chem Engn, NL-9747 AG Groningen, Netherlands

[2] Kyushu Univ, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan

[3] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS I | 2004年 / 233卷

关键词：

spin crossover; Fe(III); dithiocarbamate; thiosemicarbazone; Schiff base;

D O I：

10.1007/b95409

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-beta-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.

引用

页码：259 / 324

页数：66

共 223 条

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