Linear, redox-active Pt6 and Pt2Pd2Pt2 clusters

被引：61

作者：

Goto, E

Begum, RA

Zhan, SZ

Tanase, T

Tanigaki, K

Sakai, K

机构：

[1] Department of Chemistry, Faculty of Science, Nara Women's University, Nara 630-8285, Kitauoya-higashi-machi

[2] Department of Physics, Graduate School of Science, Tohoku University, Aoba-ku

[3] CREST, JST

[4] Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Shinjuku-ku, Tokyo 162-8601

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 38期

关键词：

cluster compounds; oxidation; palladium; platinum; redox chemistry;

D O I：

10.1002/anie.200460707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A piece of jewelry is the complex [Pt4M2(μ-H) (μ-dpmp)4(XylNC)2](PF6)3 (M = Pt, see structure), which contains the longest platinum chain characterized so far. This complex and the related compound with M = Pd are redox-active and can be readily oxidized to the electron-deficient clusters [Pt4M 2(μ-dpmp)4(XylNC)2](PF6) 4 (M = Pt, Pd) with dynamic structural changes in the metal strings. Xyl = 2,6-dimethylphenyl, dpmp = bis(diphenylphosphanylmethyl)phenylphosphane.

引用

收藏

页码：5029 / 5032

页数：4

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