Highly chemo- and regio-selective [2+2+2] cycloaddition of unsymmetrical 1,6-diynes with terminal alkynes catalyzed by Cp*Ru(cod)Cl under mild conditions

被引：105

作者：

Yamamoto, Y ^{[1
]}

Ogawa, R ^{[1
]}

Itoh, K ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 07期

关键词：

D O I：

10.1039/b000466i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ru(II)-catalyzed cycloaddition of unsymmetrical 1,6-diynes gives the desired cycloadducts in high yields with a regioselectivity meta : ortho = 88 : 12-98 : 2.

引用

页码：549 / 550

页数：2

共 30 条

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