Photochemical Modulation of Europium Ion Fluorescence Using a Tetraazamacrocyclic Derivative Bearing a Spirobenzopyran and Three Carboxymethyl Moieties

被引:3
作者
Machitani, Koji [1 ]
Nakahara, Yoshio [1 ]
Kimura, Keiichi [1 ]
机构
[1] Wakayama Univ, Fac Syst Engn, Dept Appl Chem, Wakayama 6408510, Japan
关键词
CROWN-ETHER; METAL-IONS; LUMINESCENCE; COMPLEX; PHOTOCHROMISM;
D O I
10.1246/bcsj.82.472
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The fluorescence properties of a Eu3+ complex with a tetraazamacrocyclic derivative bearing a spirobenzopyran and three carboxymethyl moieties were investigated. The enhanced fluorescence of Eu3+, which proved that the spirobenzopyran moiety worked as an antenna for the sensitization, was controlled photochemically.
引用
收藏
页码:472 / 474
页数:3
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