Pd-catalyzed cross-coupling reactions of the cycloadducts from 3,5-dibromo-2-pyrone and their synthetic applications towards various mono- and polycyclic compounds

被引：11

作者：

Lee, HS ^{[1
]}

Kim, D ^{[1
]}

Won, H ^{[1
]}

Choi, JH ^{[1
]}

Lee, H ^{[1
]}

Cho, CG ^{[1
]}

机构：

[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(02)01126-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bicylolactones from Diels-Alder (D A) cycloadditions of 3,5-dibromo-2-pyrone can undergo various palladium catalyzed cross Coupling reactions to afford a series of alkenyl, alkynyl and aryl bicyclolactones. The resulting coupled products can be readily converted into various 3-OH cyclohexenes via lactone ring openings, while those bearing dienyl units underwent highly diastereoselective D-A cycloadditions with selected dienophiles to furnish multiply functionalized polycarbocycles. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：5591 / 5595

页数：5

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