Pore-sealing by etch-byproduct followed by ALD-Ta adhesion layer for Cu/porous low-k interconnects

被引:14
作者
Furuya, A [1 ]
Soda, E [1 ]
Yoneda, K [1 ]
Yoshie, T [1 ]
Okamura, H [1 ]
Shimada, M [1 ]
Ohtsuka, N [1 ]
Ogawa, S [1 ]
机构
[1] Semicond Leading Edge Technol Inc, Res Dept 2, Tsukuba, Ibaraki 3058569, Japan
来源
PROCEEDINGS OF THE IEEE 2004 INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE | 2004年
关键词
D O I
10.1109/IITC.2004.1345677
中图分类号
TP3 [计算技术、计算机技术];
学科分类号
0812 ;
摘要
Increase of process steps by pore-sealing and low via yield by low adhesion between Cu and barrier metal are cost issues when atomic layer deposited (ALD) barrier metal process is integrated into Cu/porous low-k interconnects. In order to solve these issues, etch-byproduct in-situ deposited on the sidewall and ALD-Ta are proposed. The etch-byproduct successfully prevented Ta penetration into the porous low-k film without increase process steps. ALD-Ta film of 0.8 nm, deposited by exposures of pentakisdimethylaminotantalium. (PDMAT) and He/H-2 plasma to the substrate in turn, demonstrated strong adhesion layer as same as the conventional PVD barrier. Via yield of single damascene Cu/porous low-k interconnects with the etch-byproduct was improved by substituting ALD-Ta for ALD-TaN.
引用
收藏
页码:39 / 41
页数:3
相关论文
共 10 条
[1]  
BASCERI C, 2003, IN PRESS PROF AMC
[2]  
BESLING WFA, 2003, IN PRESS P AMC
[3]  
CHEN L, 2003, IN PRESS P AMC
[4]  
CHUNG H, 2003, P ISSM 2003
[5]   Diffusion barrier properties of transition metal thin films grown by plasma-enhanced atomic-layer deposition [J].
Kim, H ;
Cabral, C ;
Lavoie, C ;
Rossnagel, SM .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2002, 20 (04) :1321-1326
[6]   Porous low k pore sealing process study for 65-nm and below technologies [J].
Mourier, T ;
Jousseaume, V ;
Fusalba, F ;
Lecornec, C ;
Maury, P ;
Passemard, G ;
Haumesser, PH ;
Maîtrejean, S ;
Cordeau, M ;
Pantel, R ;
Pierre, F ;
Fayolle, M ;
Feldis, H .
PROCEEDINGS OF THE IEEE 2003 INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE, 2003, :245-247
[7]  
OHTAKE H, 2002, P IEDM 2002, P599
[8]   Plasma-enhanced atomic layer deposition of Ta and Ti for interconnect diffusion barriers [J].
Rossnagel, SM ;
Sherman, A ;
Turner, F .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2000, 18 (04) :2016-2020
[9]  
Tada M, 2003, 2003 IEEE INTERNATIONAL ELECTRON DEVICES MEETING, TECHNICAL DIGEST, P845
[10]   Investigation of copper agglomeration at elevated temperatures [J].
Yang, CY ;
Chen, JS .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) :G826-G830