Geometry-tunable Lewis acidity of amidinium cations and its relevance to redox reactions of the Thauer metal-free hydrogenase: A theoretical study

被引：16

作者：

Cioslowski, J

Boche, G

机构：

[1] FLORIDA STATE UNIV,SUPERCOMP COMPUTAT RES INST,TALLAHASSEE,FL 32306

[2] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1997年 / 36卷 / 1-2期

关键词：

carbocations; enzymes; hydrogenases; thermodynamics;

D O I：

10.1002/anie.199701071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：107 / 109

页数：3

共 29 条

[11] UNDERSTANDING THE RATES OF CERTAIN ENZYME-CATALYZED REACTIONS - PROTON ABSTRACTION FROM CARBON ACIDS, ACYL-TRANSFER REACTIONS, AND DISPLACEMENT-REACTIONS OF PHOSPHODIESTERS
GERLT, JA
GASSMAN, PG
[J]. BIOCHEMISTRY, 1993, 32 (45) : 11943 - 11952
[12] HOGEVEEN H, 1968, RECL TRAV CHIM PAY-B, V87, P319
[13] MANDELATE RACEMASE - STRUCTURE-FUNCTION STUDIES OF A PSEUDOSYMMETRIC ENZYME
KENYON, GL
GERLT, JA
PETSKO, GA
KOZARICH, JW
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (04) : 178 - 186
[14] A COMPARISON OF MODEL CHEMISTRIES
OCHTERSKI, JW
PETERSSON, GA
WIBERG, KB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (45) : 11299 - 11308
[15] Olah G. A., 1995, ANGEW CHEM, V107, P1519
[16] Olah G. A., 1985, Superacids
[17] Olah G. A., 1968, Carbonium Ions, VI
[18] MY SEARCH FOR CARBOCATIONS AND THEIR ROLE IN CHEMISTRY (NOBEL LECTURE)
OLAH, GA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14): : 1393 - 1405
[19] SUPERELECTROPHILES
OLAH, GA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (06): : 767 - 788
[20] Olah GA, 1993, ANGEW CHEM, V105, P805