On the existence of a nickel hydroxide phase which is neither alpha nor beta

被引:89
作者
Rajamathi, M
Subbanna, GN
Kamath, PV
机构
[1] BANGALORE UNIV,CENT COLL,DEPT CHEM,BANGALORE 560001,KARNATAKA,INDIA
[2] INDIAN INST SCI,CTR MAT RES,BANGALORE 560012,KARNATAKA,INDIA
关键词
D O I
10.1039/a700390k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel phase of nickel hydroxide with an average interlayer spacing 5.4-5.6 Angstrom has been synthesized which is neither ct nor beta type but is an interstratification of both. It ages to the beta form in strong alkali. These observations have implications on the dissolution-reprecipitation mechanism suggested for the alpha-->beta transformation of nickel hydroxide.
引用
收藏
页码:2293 / 2296
页数:4
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