4,9-Dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b′]dithiophene as a π-Spacer of Donor-π-Acceptor Dye and Its Photovoltaic Performance with Liquid and Solid-State Dye-Sensitized Solar Cells

被引：45

作者：

Cai, Liping ^{[1
]}

Moehl, Thomas ^{[2
]}

Moon, Soo-Jin ^{[2
]}

Decoppet, Jean-David ^{[2
]}

Humphry-Baker, Robin ^{[2
]}

Xue, Zhaosheng ^{[1
]}

Bin, Liu ^{[1
]}

Zakeeruddin, Shaik M. ^{[2
]}

Graetzel, Michael ^{[2
]}

机构：

[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117576, Singapore

[2] Swiss Fed Inst Technol, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 01期

基金：

瑞士国家科学基金会; 欧洲研究理事会;

关键词：

CHARGE RECOMBINATION; HIGH-EFFICIENCY; ELECTROLYTE; TRANSPORT;

D O I：

10.1021/ol402749s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new D-pi-A organic dye, LC-5, containing 4,9-dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b']-dithiophene as a novel pi-conjugated spacer has been synthesized and tested as a sensitizer in dye-sensitized solar cells (DSC). Volatile and ionic liquid electrolytes have been used in conjunction with the synthesized dye, and the electrolyte influence on the photovoltaic performance of DSCs was investigated. A detailed investigation, including transient photocurrent/photovoltage decay measurements and electrochemical impedance spectroscopy data, provide important conclusions about the influence of electrolytes on the photovoltaic parameters.

引用

页码：106 / 109

页数：4

共 27 条

[1] A novel metal-free panchromatic TiO2 sensitizer based on a phenylenevinylene-conjugated unit and an indoline derivative for highly efficient dye-sensitized solar cells [J].

Akhtaruzzaman, Md ;

Islam, Ashraful ;

Yang, Fan ;

Asao, Naoki ;

Kwon, Eunsang ;

Singh, Surya Prakash ;

Han, Liyuan ;

Yamamoto, Yoshinori .

CHEMICAL COMMUNICATIONS, 2011, 47 (45) :12400-12402

[2] Highly Efficient Mesoscopic Dye-Sensitized Solar Cells Based on Donor-Acceptor-Substituted Porphyrins [J].

Bessho, Takeru ;

Zakeeruddin, Shaik M. ;

Yeh, Chen-Yu ;

Diau, Eric Wei-Guang ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (37) :6646-6649

[3] A strategy to design highly efficient porphyrin sensitizers for dye-sensitized solar cells [J].

Chang, Yu-Cheng ;

Wang, Chin-Li ;

Pan, Tsung-Yu ;

Hong, Shang-Hao ;

Lan, Chi-Ming ;

Kuo, Hshin-Hui ;

Lo, Chen-Fu ;

Hsu, Hung-Yu ;

Lin, Ching-Yao ;

Diau, Eric Wei-Guang .

CHEMICAL COMMUNICATIONS, 2011, 47 (31) :8910-8912

[4] Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells [J].

Chen, Chia-Yuan ;

Wang, Mingkui ;

Li, Jheng-Ying ;

Pootrakulchote, Nuttapol ;

Alibabaei, Leila ;

Ngoc-le, Cevey-ha ;

Decoppet, Jean-David ;

Tsai, Jia-Hung ;

Graetzel, Carole ;

Wu, Chun-Guey ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

ACS NANO, 2009, 3 (10) :3103-3109

[5] Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy [J].

Fabregat-Santiago, F ;

Bisquert, J ;

Garcia-Belmonte, G ;

Boschloo, G ;

Hagfeldt, A .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) :117-131

[6] Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy [J].

Fabregat-Santiago, Francisco ;

Garcia-Belmonte, Germa ;

Mora-Sero, Ivan ;

Bisquert, Juan .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (20) :9083-9118

[7] Recent Advances in Sensitized Mesoscopic Solar Cells [J].

Graetzel, Michael .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1788-1798

[8] Dye-Sensitized Solar Cells [J].

Hagfeldt, Anders ;

Boschloo, Gerrit ;

Sun, Licheng ;

Kloo, Lars ;

Pettersson, Henrik .

CHEMICAL REVIEWS, 2010, 110 (11) :6595-6663

[9] High efficiency of dye-sensitized solar cells based on metal-free indoline dyes [J].

Horiuchi, T ;

Miura, H ;

Sumioka, K ;

Uchida, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (39) :12218-12219

[10] Unsymmetrical Squaraines Incorporating Quinoline for Near Infrared Responsive Dye-Sensitized Solar Cells [J].

Li, Jheng-Ying ;

Chen, Chia-Yuan ;

Ho, Wen-Chein ;

Chen, Szu-Han ;

Wu, Chun-Guey .

ORGANIC LETTERS, 2012, 14 (21) :5420-5423

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