Ti 2p and O 1s core levels and chemical bonding in titanium-bearing oxides

被引：290

作者：

Atuchin, Victor V. ^{[1
]}

Kesler, Valery G.

Pervukhina, Natalia V.

Zhang, Zhaoming

机构：

[1] Russian Acad Sci, Inst Semicond Phys, SB, Lab Opt Mat & Struct, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Inst Semicond Phys, SB, Ctr Tech, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Inst Inorgan Chem, SB, Lab Crystal Chem, Novosibirsk 630090, Russia

[4] Australian Nucl Sci & Technol Org, Menai, NSW 2234, Australia

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2006年 / 152卷 / 1-2期

关键词：

titanates; chemical bonding; XPS;

D O I：

10.1016/j.elspec.2006.02.004

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A set of available experimental data on the binding energies of Ti 2p(3/2) and 0 Is core levels in titanium-bearing oxides has been presented by using the binding energy difference (0 1s-Ti 2P(3/2)) as a robust parameter to characterize these compounds. An empirical relationship between the (0 1s-Ti 2P(3/2)) values measured with XPS and the mean chemical bond length L(Ti-O) in these crystals has been discussed for Ti4+-compounds. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：18 / 24

页数：7

共 94 条

[11] Mechanisms responsible for chemical shifts of core-level binding energies and their relationship to chemical bonding [J].

Bagus, PS ;

Illas, F ;

Pacchioni, G ;

Parmigiani, F .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1999, 100 :215-236

[12] RECENT ADVANCES IN X-RAY PHOTOELECTRON-SPECTROSCOPY STUDIES OF OXIDES [J].

BARR, TL .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1991, 9 (03) :1793-1805

[13] Calcium phosphate interactions with titanium oxide and alumina substrates:: an XPS study [J].

Barrère, F ;

Lebugle, A ;

Van Blitterswijk, CA ;

De Groot, K ;

Layrolle, P ;

Rey, C .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2003, 14 (05) :419-425

[14] Electronic structure of titanium monoxide [J].

Bartkowski, S ;

Neumann, M ;

Kurmaev, EZ ;

Fedorenko, VV ;

Shamin, SN ;

Cherkashenko, VM ;

Nemnonov, SN ;

Winiarski, A ;

Rubie, DC .

PHYSICAL REVIEW B, 1997, 56 (16) :10656-10667

[15] THE STRUCTURAL CHARACTERIZATION OF SN0.5NBTIP3O12 AND FE0.33NBTIP3O12 [J].

BERRY, FJ ;

GREAVES, C ;

MARCO, JF .

JOURNAL OF SOLID STATE CHEMISTRY, 1992, 96 (02) :408-414

[16] A NEUTRON POWDER INVESTIGATION OF THE HIGH-TEMPERATURE PHASE-TRANSITION IN NITIO3 [J].

BOYSEN, H ;

FREY, F ;

LERCH, M ;

VOGT, T .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1995, 210 (05) :328-337

[17]

Briggs D., 1994, AUGER XRAY PHOTOELEC, V1

[18] STRUCTURAL PARAMETERS AND ELECTRON DIFFERENCE DENSITY IN BATIO3 [J].

BUTTNER, RH ;

MASLEN, EN .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1992, 48 :764-769

[19] THE IDENTIFICATION AND CHARACTERIZATION OF MIXED OXIDATION-STATES AT OXIDIZED TITANIUM SURFACES BY ANALYSIS OF X-RAY PHOTOELECTRON-SPECTRA [J].

CARLEY, AF ;

CHALKER, PR ;

RIVIERE, JC ;

ROBERTS, MW .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 :351-370

[20] Thermal behaviour of ultra-thin Co overlayers on rutile TiO2(100) surface [J].

Chai, JW ;

Pan, JS ;

Wang, SJ ;

Huan, CHA ;

Lau, GS ;

Zheng, YB ;

Xu, S .

SURFACE SCIENCE, 2005, 589 (1-3) :32-41

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