Carbon nanofibers prepared by the carbonization of self-assembled cellulose nanocrystals

被引:17
作者
Cho, Se Youn [1 ]
Yun, Young Soo [1 ]
Jin, Hyoung-Joon [1 ]
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
基金
新加坡国家研究基金会;
关键词
cellulose nanocrystals; self-assembly; carbonization; carbon fibers; ACID-HYDROLYSIS; MICROCRYSTALLINE CELLULOSE; WHISKERS; NANOCOMPOSITES; NANOPARTICLES; NANOTUBES; BEHAVIOR; SIZE;
D O I
10.1007/s13233-014-2094-x
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
In this study, we fabricated fibrous carbon materials by using self-assembled cellulose nanocrystal fibers as the precursor. Cellulose nanocrystals at low concentrations, which were isolated from commercial microcystallline cellulose by a sulfuric acid treatment, were self-assembled into fibrous cellulose particles during the frozen process. After a stabilization process, the cellulose nanocrystal fibers were carbonized at 1,000 A degrees C. Field-emission scanning electron microscopy, Raman spectroscopy, and wide-angle X-ray diffraction analysis were used to confirm the formation of amorphous carbon fibers from the cellulose nanocrystal fibers.
引用
收藏
页码:753 / 756
页数:4
相关论文
共 24 条
[1]
Flow properties of microcrystalline cellulose suspension prepared by acid treatment of native cellulose [J].
Araki, J ;
Wada, M ;
Kuga, S ;
Okano, T .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 142 (01) :75-82
[2]
COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS [J].
BETHUNE, DS ;
KIANG, CH ;
DEVRIES, MS ;
GORMAN, G ;
SAVOY, R ;
VAZQUEZ, J ;
BEYERS, R .
NATURE, 1993, 363 (6430) :605-607
[3]
Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis [J].
Bondeson, D ;
Mathew, A ;
Oksman, K .
CELLULOSE, 2006, 13 (02) :171-180
[4]
Cellulose poly(ethylene-co-vinyl acetate) nanocomposites studied by molecular modeling and mechanical spectroscopy [J].
Chauve, G ;
Heux, L ;
Arouini, R ;
Mazeau, K .
BIOMACROMOLECULES, 2005, 6 (04) :2025-2031
[5]
Cellulose nanowhisker foams by freeze casting [J].
Dash, Rajalaxmi ;
Li, Yang ;
Ragauskas, Arthur J. .
CARBOHYDRATE POLYMERS, 2012, 88 (02) :789-792
[6]
Carbon fibres from cellulosic precursors: a review [J].
Dumanli, Ahu Guemrah ;
Windle, Alan H. .
JOURNAL OF MATERIALS SCIENCE, 2012, 47 (10) :4236-4250
[7]
The shape and size distribution of crystalline nanoparticles prepared by acid hydrolysis of native cellulose [J].
Elazzouzi-Hafraoui, Samira ;
Nishiyama, Yoshiharu ;
Putaux, Jean-Luc ;
Heux, Laurent ;
Dubreuil, Frdric ;
Rochas, Cyrille .
BIOMACROMOLECULES, 2008, 9 (01) :57-65
[8]
POLYMER NANOCOMPOSITES REINFORCED BY CELLULOSE WHISKERS [J].
FAVIER, V ;
CHANZY, H ;
CAVAILLE, JY .
MACROMOLECULES, 1995, 28 (18) :6365-6367
[9]
Acid hydrolysis of some industrial pulps:: effect of hydrolysis conditions and raw material [J].
Håkansson, H ;
Ahlgren, P .
CELLULOSE, 2005, 12 (02) :177-183
[10]
Self-Assembling Behavior of Cellulose Nanoparticles during Freeze-Drying: Effect of Suspension Concentration, Particle Size, Crystal Structure, and Surface Charge [J].
Han, Jingquan ;
Zhou, Chengjun ;
Wu, Yiqiang ;
Liu, Fangyang ;
Wu, Qinglin .
BIOMACROMOLECULES, 2013, 14 (05) :1529-1540