Metallomicellar supramolecular systems and their applications in catalytic reactions

被引：79

作者：

Zhang, Ji ^{[1
]}

Meng, Xiang-Guang ^{[1
]}

Zeng, Xian-Cheng ^{[1
]}

Yu, Xiao-Qi ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 17-18期

基金：

中国国家自然科学基金;

关键词：

Metallomicellar catalysis; Hydrolysis; Kinetic model; Chiral catalysis; Enantioselectivity; P-NITROPHENYL PICOLINATE; AMINO-ACID ESTERS; HYDROLYTIC METALLOENZYME MODELS; DIELS-ALDER REACTION; SURFACTANT-COMBINED CATALYSTS; CHIRAL LIPOPHILIC LIGANDS; LEWIS-ACID; ASYMMETRIC HYDROGENATION; ORGANIC-REACTIONS; ENANTIOSELECTIVE HYDROLYSIS;

D O I：

10.1016/j.ccr.2008.11.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review presents advances in metallomicelles-catalyzed reactions, including hydrolysis of carboxylic esters and phosphates, oxidation-reductions, C-C bond forming reactions, etc. These novel supramolecular vehicles can not only mimic the active center, but also the hydrophobic microenvironments of metalloenzymes. As emphasis, the kinetic models and mechanism studies of metallomicelles-catalyzed hydrolysis, which were intensively studied in our group, were particularly reviewed. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2166 / 2177

页数：12

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