Photo-physical characterization of rhodamine 6G in a 2-hydroxyethyl-methacrylate methyl-methacrylate copolymer

被引:61
作者
Holzer, W
Gratz, H
Schmitt, T
Penzkofer, A
Costela, A
García-Moreno, I
Sastre, R
Duarte, FJ
机构
[1] Univ Regensburg, Inst Expt & Angew Phys 2, D-93040 Regensburg, Germany
[2] CSIC, Inst Quim Fis Rocasolano, E-28006 Madrid, Spain
[3] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain
[4] Eastman Kodak Co, Rochester, NY 14630 USA
关键词
solid-state dye laser material; dye-doped polymer; rhodamine; 6G; HEMA-MMA copolymer; fluorescence analysis; adsorption spectra; photo-degradation; saturable absorption; excited-state absorption;
D O I
10.1016/S0301-0104(00)00101-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Some photo-physical parameters of 1 x 10(-4) and 5.9 x 10(-4) M samples of rhodamine 6G in a 2-hydroxyethyl-methacrylate methyl-methacrylate copolymer (volume mixture 1:1) are determined and compared with rhodamine 6G in methanol. They include the absorption cross-section and stimulated emission cross-section spectra, the fluorescence quantum distributions, quantum yields and lifetimes. The photo-degradation under steady-state and pulsed excitation is investigated. The saturable absorption behaviour under picosecond laser excitation is studied. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:125 / 136
页数:12
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