Vibrational Coherences and Relaxation in the High-Spin State of Aqueous [FeII(bpy)3]2+

被引：153

作者：

Consani, Cristina ^{[1
]}

Premont-Schwarz, Mirabelle ^{[1
]}

ElNahhas, Amal ^{[1
]}

Bressler, Christian ^{[1
]}

van Mourik, Frank ^{[1
]}

Cannizzo, Andrea ^{[1
]}

Chergui, Majed ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, LSU, ISIC, Fac Sci Base,BSP, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 39期

关键词：

iron; spin crossover; time-resolved spectroscopy; ultrafast dynamics; vibrational relaxation; RAMAN-SPECTROSCOPY; DFT CALCULATIONS; CROSSOVER; COMPLEXES; IRON(II); DYNAMICS; SPECTRA;

D O I：

10.1002/anie.200902728

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dizzy cooling: Femtosecond excitation of the singlet states of aqueous [FeII(bpy)3]2+ (bpy=2,2′ - bipyridine) leads to the formation of a vibrationally hot quintet state that exhibits wave-packet dynamics arising from a chelate-ring and bending mode. The vibrational relaxation involves at least two modes: the Fe - N stretching mode (see picture) and the coherently excited chelatering and bending mode, which relax on different time scales. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：7184 / 7187

页数：4

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