Enhancement of Chemical Stability and Crystallinity in Porphyrin-Containing Covalent Organic Frameworks by Intramolecular Hydrogen Bonds

被引：462

作者：

Kandambeth, Sharath ^{[1
]}

Shinde, Digambar Balaji ^{[1
]}

Panda, Manas K. ^{[1
]}

Lukose, Binit ^{[2
]}

Heine, Thomas ^{[2
]}

Banerjee, Rahul ^{[1
]}

机构：

[1] CSIR Natl Chem Lab, Phys Mat Chem Div, Pune 411008, Maharashtra, India

[2] Jacobs Univ Bremen, Ctr Funct Nanomat, Sch Sci & Engn, D-28759 Bremen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 49期

基金：

欧洲研究理事会;

关键词：

covalent organic frameworks; hydrogen bonds; mesoporous materials; porphyrinoids; tautomerism; DESIGN; BASE;

D O I：

10.1002/anie.201306775

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A strong bond: A strategy based on intramolecular hydrogen-binding interactions in 2D covalent organic frameworks (COFs) is shown to improve the crystallinity, porosity, and chemical stability of the material (see picture). The concept is validated by removing the hydrogen-bonding interaction in the methoxy analog which showed a lower stability and crystallinity. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13052 / 13056

页数：5

共 33 条

[1] [Anonymous], 1996, CRYSTAL STRUCTURE I
[2] Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
Ben, Teng
Ren, Hao
Ma, Shengqian
Cao, Dapeng
Lan, Jianhui
Jing, Xiaofei
Wang, Wenchuan
Xu, Jun
Deng, Feng
Simmons, Jason M.
Qiu, Shilun
Zhu, Guangshan
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) : 9457 - 9460
[3] From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities
Bhunia, Asamanjoy
Vasylyeva, Vera
Janiak, Christoph
[J]. CHEMICAL COMMUNICATIONS, 2013, 49 (38) : 3961 - 3963
[4] Control of Crystallinity and Porosity of Covalent Organic Frameworks by Managing Interlayer Interactions Based on Self-Complementary π-Electronic Force
Chen, Xiong
Addicoat, Matthew
Irle, Stephan
Nagai, Atsushi
Jiang, Donglin
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (02) : 546 - 549
[5] Rationally synthesized two-dimensional polymers
Colson, John W.
Dichtel, William R.
[J]. NATURE CHEMISTRY, 2013, 5 (06) : 453 - 465
[6] Porous, crystalline, covalent organic frameworks
Côté, AP
Benin, AI
Ockwig, NW
O'Keeffe, M
Matzger, AJ
Yaghi, OM
[J]. SCIENCE, 2005, 310 (5751) : 1166 - 1170
[7] REACTIONS OF COORDINATED LIGANDS .I. KINETICS AND MECHANISM OF HYDROLYSIS OF N-SALICYLIDENEANILINE IN PRESENCE OF METAL IONS
DASH, AC
NANDA, RK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (25) : 6944 - &
[8] Desiraju G. R., 1999, The Weak Hydrogen Bond
[9] Di Bernardo P, 2006, DALTON T, P4711, DOI 10.1039/b604211b
[10] Covalent organic frameworks (COFs): from design to applications
Ding, San-Yuan
Wang, Wei
[J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (02) : 548 - 568

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