Regio- and stereocontrolled hydrosilylation polyaddition catalyzed by RhI(PPh3)3.: Syntheses of polymers containing (E)- or (Z)-alkenylsilane moieties

被引：70

作者：

Mori, A ^{[1
]}

Takahisa, E

Kajiro, H

Nishihara, Y

Hiyama, T

机构：

[1] Tokyo Inst Technol, Res Lab Resources Utilizat, Yokohama, Kanagawa 2268503, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan

来源：

MACROMOLECULES | 2000年 / 33卷 / 04期

关键词：

D O I：

10.1021/ma9913360

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Stereodivergent syntheses of E- and Z-polymers of the alkenylsilane moiety were carried out hand in hand by hydrosilation polyaddition using diethylbenzene and bis(dimethylsily)benzene. Spectroscopic change based on the stereochemistries of polymers was observed.

引用

页码：1115 / 1116

页数：2

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