Hydroxylated Graphene-Sulfur Nanocomposites for High-Rate Lithium-Sulfur Batteries

被引:398
作者
Zu, Chenxi [1 ]
Manthiram, Arumugam [1 ]
机构
[1] Univ Texas Austin, Electrochem Energy Lab, Mat Sci & Engn Program, Austin, TX 78712 USA
关键词
amorphous sulfur; electrochemical performance; hydroxylated graphene; lithium-sulfur batteries; CATHODE; OXIDE; CELL;
D O I
10.1002/aenm.201201080
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A hydroxylated graphene-S nanocomposite exhibiting superior electrochemical performance at high rates is developed through a facile chemical deposition method at room temperature. The hydroxyl groups in graphene can interact with the sulfur-containing compounds, rendering sulfur in the amorphous state during the chemical deposition reaction and preventing polysulfide dissolution during cycling. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1008 / 1012
页数:5
相关论文
共 37 条
  • [1] Li/S fundamental chemistry and application to high-performance rechargeable batteries
    Akridge, JR
    Mikhaylik, YV
    White, N
    [J]. SOLID STATE IONICS, 2004, 175 (1-4) : 243 - 245
  • [2] [Anonymous], SPECTROSCOPY OF RUBB
  • [3] Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification
    Barchasz, Celine
    Molton, Florian
    Duboc, Carole
    Lepretre, Jean-Claude
    Patoux, Sebastien
    Alloin, Fannie
    [J]. ANALYTICAL CHEMISTRY, 2012, 84 (09) : 3973 - 3980
  • [4] Nanomaterials for rechargeable lithium batteries
    Bruce, Peter G.
    Scrosati, Bruno
    Tarascon, Jean-Marie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
  • [5] Coates J., 2000, INTERPRETATION OF IN
  • [6] Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries
    Elazari, Ran
    Salitra, Gregory
    Garsuch, Arnd
    Panchenko, Alexander
    Aurbach, Doron
    [J]. ADVANCED MATERIALS, 2011, 23 (47) : 5641 - +
  • [7] Graphene-enveloped sulfur in a one pot reaction: a cathode with good coulombic efficiency and high practical sulfur content
    Evers, Scott
    Nazar, Linda F.
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (09) : 1233 - 1235
  • [8] Chemically bonded graphene/BiOCl nanocomposites as high-performance photocatalysts
    Gao, Feidan
    Zeng, Dawen
    Huang, Qingwu
    Tian, Shouqin
    Xie, Changsheng
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (30) : 10572 - 10578
  • [9] Challenges for Rechargeable Li Batteries
    Goodenough, John B.
    Kim, Youngsik
    [J]. CHEMISTRY OF MATERIALS, 2010, 22 (03) : 587 - 603
  • [10] Sulfur-Impregnated Disordered Carbon Nanotubes Cathode for Lithium-Sulfur Batteries
    Guo, Juchen
    Xu, Yunhua
    Wang, Chunsheng
    [J]. NANO LETTERS, 2011, 11 (10) : 4288 - 4294