Synthesis, X-ray structure, and properties of the singly bonded C60 dimer having diethoxyphosphorylmethyl groups utilizing the chemistry of C602-

被引：83

作者：

Cheng, FY ^{[1
]}

Murata, Y ^{[1
]}

Komatsu, K ^{[1
]}

机构：

[1] Kyoto Univ, Chem Res Inst, Uji, Kyoto 6110011, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 15期

关键词：

D O I：

10.1021/ol026281s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A singly bonded C-60 dimer having a diethoxyphosphorylmethyl group on each C-60 cage was obtained by the reaction of C-60(2-) dianion with diethyl iodomethylphosphonate followed by the treatment with iodine. The precise structure of the dimer was determined for the first time by X-ray crystallography, and its homolytic dissociation as well as spectroscopic and electrochemical properties were clarified.

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页码：2541 / 2544

页数：4

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