Surface-oxidized carbon fibers .1. Surface structure and chemistry

被引:719
作者
Zielke, U [1 ]
Huttinger, KJ [1 ]
Hoffman, WP [1 ]
机构
[1] PHILLIPS LAB,EDWARDS AFB,CA 93524
关键词
carbon fibers; surface structure; surface chemistry; adsorbed oxidation products; scanning tunneling microscopy; contact angle measurements; X-ray photoelectron spectroscopy; temperature-programmed desorption;
D O I
10.1016/0008-6223(96)00032-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The surface structure and chemistry of various surface oxidized HT carbon fibers, an IM and a HM carbon fiber were studied by SEM, STM, CAM (contact angle measurement), XPS and TPD with special reference to adsorbed oxidation products and adsorbed water. It is shown that a real image of surface structure and surface chemistry is only obtained after removal of adsorbed oxidation products by extraction with water and careful drying of the fibers without changing the surface chemistry. A comparison on the usefulness of the various surface analytical methods will be given in Parts II-IV of this paper. Copyright (C) 1996 Elsevier Science Ltd
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页码:983 / 998
页数:16
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