A square-planar organoiron(III) compound with a spin-admixed state

被引：42

作者：

Alonso, Pablo J.

Arauzo, Ana B.

Fornies, Juan

Garcia-Monforte, M. Angeles

Martin, Antonio

Martinez, Jesus I.

Menjon, Babil

Rillo, Conrado

Saiz-Garitaonandia, Jose J.

机构：

[1] Univ Zaragoza, Inst Ciencia Mat Aragon, Zaragoza, Spain

[2] CSIC, Zaragoza, Spain

[3] Univ Basque Country, Fac Ciencias & Tecnol, Dept Fis Aplicada 2, E-48080 Bilbao, Spain

[4] Univ Zaragoza, Serv Instrumentac Cient, Zaragoza, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 40期

关键词：

EPR spectroscopy; homoleptic compounds; iron; magnetic properties; Moessbauer spectroscopy;

D O I：

10.1002/anie.200601774

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Square-planar iron(III) species bearing no axial ligands can still behave as spin-admixed systems (S=3/2,5/2). The highly unusual homoleptic σ-organoiron complex [Li(thf)4][Fe III(C6Cl5)4] (see anion in picture; green Cl, gray C) is an example of such a system. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6707 / 6711

页数：5

共 35 条

[1] Synthesis and first structural characterisation of a homoleptic tetraorganochromate(III) salt
Alonso, PJ
Falvello, LR
Forniés, J
García-Monforte, MA
Martín, A
Menjón, B
Rodríguez, G
[J]. CHEMICAL COMMUNICATIONS, 1998, (16) : 1721 - 1722
[2] Alonso PJ, 2002, CHEM-EUR J, V8, P4056, DOI 10.1002/1521-3765(20020902)8:17<4056::AID-CHEM4056>3.0.CO
[3] 2-Q
[4] Alvarez S., 2006, ANGEW CHEM, V118, P3078
[5] How high the spin? Allowed and forbidden spin states in transition-metal chemistry
Alvarez, Santiago
Cirera, Jordi
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (19) : 3012 - 3020
[6] Direct incorporation of a ferric ion in the porphyrinogen core: tetrakis(cyclohexyl)iron porphyrinogen anion with different conformers and its reaction with iodine
Bhattacharya, D
Dey, S
Maji, S
Pal, K
Sarkar, S
[J]. INORGANIC CHEMISTRY, 2005, 44 (22) : 7699 - 7701
[7] Iron-catalyzed reactions in organic synthesis
Bolm, C
Legros, J
Le Paih, J
Zani, L
[J]. CHEMICAL REVIEWS, 2004, 104 (12) : 6217 - 6254
[8] PERIODIC ORBITS FOR HYPERBOLIC FLOWS
BOWEN, R
[J]. AMERICAN JOURNAL OF MATHEMATICS, 1972, 94 (01) : 1 - &
[9] MOSSBAUER ABSORPTION IN PRESENCE OF ELECTRON SPIN RELAXATION
BRADFORD, E
MARSHALL, W
[J]. PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1966, 87 (557P): : 731 - &
[10] MAGNETOCHEMISTRY OF IONS IN THE 4A2 ELECTRONIC STATE
CARLIN, RL
[J]. SCIENCE, 1985, 227 (4692) : 1291 - 1295

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