A square-planar organoiron(III) compound with a spin-admixed state

被引：42

作者：

Alonso, Pablo J.

Arauzo, Ana B.

Fornies, Juan

Garcia-Monforte, M. Angeles

Martin, Antonio

Martinez, Jesus I.

Menjon, Babil

Rillo, Conrado

Saiz-Garitaonandia, Jose J.

机构：

[1] Univ Zaragoza, Inst Ciencia Mat Aragon, Zaragoza, Spain

[2] CSIC, Zaragoza, Spain

[3] Univ Basque Country, Fac Ciencias & Tecnol, Dept Fis Aplicada 2, E-48080 Bilbao, Spain

[4] Univ Zaragoza, Serv Instrumentac Cient, Zaragoza, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 40期

关键词：

EPR spectroscopy; homoleptic compounds; iron; magnetic properties; Moessbauer spectroscopy;

D O I：

10.1002/anie.200601774

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Square-planar iron(III) species bearing no axial ligands can still behave as spin-admixed systems (S=3/2,5/2). The highly unusual homoleptic σ-organoiron complex [Li(thf)4][Fe III(C6Cl5)4] (see anion in picture; green Cl, gray C) is an example of such a system. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6707 / 6711

页数：5