Homogeneous atom transfer radical polymerization of methyl methacrylate at ambient temperature in aqueous ethanol

被引：33

作者：

Jewrajka, SK ^{[1
]}

Chatterjee, U ^{[1
]}

Mandal, BM ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Polymer Sci Unit, Kolkata 700032, W Bengal, India

来源：

MACROMOLECULES | 2004年 / 37卷 / 11期

关键词：

D O I：

10.1021/ma0497613

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The problems encountered with Atom Transfer Radical Polymerization (ATRP) conducted in media containing water while studying ATRP of acrylamide in aqueous glycerol were discussed. It was shown that the R-Br+CuBr/L initiator catalyst system gave a higher rate of polymerization than the R-Cl+CuCl/L with MMA while the opposite was true for acrylamide. It was found that the equilibrium constant for the reversible deactivation K=ka/kda was greater for a Br based system in the ATRP of MMA, but the reverse was true in the ATRP of acrylamide. The analysis shows that ATRP of MMA was facile and well controlled at ambient temperature in the environment friendly solvent, aqueous ethanol, using the CuX/o-phen catalyst system.

引用

页码：4325 / 4328

页数：4

共 36 条

[1]

[Anonymous], POLYM PREPR

[2] KINETICS OF THE POLYMERIZATION OF METHYL METHACRYLATE IN AQUEOUS SOLUTION [J].

ATKINSON, B ;

COTTEN, GR .

TRANSACTIONS OF THE FARADAY SOCIETY, 1958, 54 (06) :877-885

[3] MODERATED COPOLYMERIZATION .4. PENULTIMATE UNIT EFFECT IN CHAIN-TRANSFER - SYSTEM STYRENE-METHYL METHACRYLATE-1-BUTANE THIOL [J].

BAMFORD, CH ;

BASAHEL, SN .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1980, 76 :107-111

[4] MODERATED CO-POLYMERIZATION .2. TRANSFER CONSTANT OF STYRYL RADICALS TOWARDS CARBON TETRABROMIDE - A PENULTIMATE UNIT EFFECT IN CHAIN TRANSFER [J].

BAMFORD, CH ;

BASAHEL, SN .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :1020-1028

[5] MODERATED COPOLYMERIZATION .5. PENULTIMATE UNIT EFFECT IN CHAIN-TRANSFER - SYSTEMS STYRENE-METHYL ACRYLATE CARBON TETRABROMIDE AND STYRENE-METHYL ACRYLATE-1-BUTANE THIOL AND SOME GENERAL-CONSIDERATIONS [J].

BAMFORD, CH ;

BASAHEL, SN .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1980, 76 :112-117

[6] EFFECTS OF SALTS OF METALS ON VINYL POLYMERIZATION .1. POLYMERIZATION OF METHYL METHACRYLATE IN PRESENCE OF CUPRIC CHLORIDE [J].

BENGOUGH, WI ;

FAIRSERV.WH .

TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (510P) :1206-&

[7] EFFECTS OF SALTS OF METALS ON VINYL POLYMERIZATION .6. POLYMERIZATION OF METHYL METHACRYLATE IN PRESENCE OF CUPRIC BROMIDE [J].

BENGOUGH, WI ;

FAIRSERV.WH .

TRANSACTIONS OF THE FARADAY SOCIETY, 1971, 67 (578) :414-&

[8] Unexpected transesterification of tertiary amine methacrylates during methanolic ATRP at ambient temperature: A cautionary tale [J].

Bories-Azeau, X ;

Armes, SP .

MACROMOLECULES, 2002, 35 (27) :10241-10243

[9]

BRANDRUP J, POLYM HDB, P244

[10] THE POLYMERIZATION OF ACRYLAMIDE IN AQUEOUS SOLUTION .2. THE EFFECT OF FERRIC PERCHLORATE ON THE X-RAY AND GAMMA-RAY INITIATED REACTION [J].

COLLINSON, E ;

DAINTON, FS ;

MCNAUGHTON, GS .

TRANSACTIONS OF THE FARADAY SOCIETY, 1957, 53 (04) :489-498

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