Unexpected transesterification of tertiary amine methacrylates during methanolic ATRP at ambient temperature: A cautionary tale

被引：73

作者：

Bories-Azeau, X ^{[1
]}

Armes, SP ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

MACROMOLECULES | 2002年 / 35卷 / 27期

关键词：

D O I：

10.1021/ma021388g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The propensity for the tertiary amine methacrylates was studied. Transesterification was performed under mild conditions in methanol. Results showed that methanol should not be used as a cosolvent for the atom transfer radical polymerization (ATRP) of 2-dimethylaminoethyl methacrylate (DMA) at the ambient temperature.

引用

页码：10241 / 10243

页数：3

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