A novel FeS cluster in Fe-only hydrogenases

被引：353

作者：

Nicolet, Y

Lemon, BJ

Fontecilla-Camps, JC

Peters, JW

机构：

[1] CEA, CNRS, Inst Biol Struct Jean Pierre Ebel, Cristallog & Cristallogenese Prot Lab, F-38027 Grenoble 1, France

[2] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA

来源：

TRENDS IN BIOCHEMICAL SCIENCES | 2000年 / 25卷 / 03期

关键词：

D O I：

10.1016/S0968-0004(99)01536-4

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Many microorganisms can use molecular hydrogen as a source of electrons or generate it by reducing protons. These reactions are catalysed by metalloenzymes of two types: NiFe and Fe-only hydrogenases. Here, we review recent structural results concerning the latter, putting special emphasis on the characteristics of the active site.

引用

页码：138 / 143

页数：6

共 31 条

[21] Peters JW, 1999, SCIENCE, V283, P35
[22] A low-spin iron with CN and CO as intrinsic ligands forms the core of the active site in [Fe]-hydrogenases
Pierik, AJ
Hulstein, M
Hagen, WR
Albracht, SPJ
[J]. EUROPEAN JOURNAL OF BIOCHEMISTRY, 1998, 258 (02): : 572 - 578
[23] CHARACTERIZATION AND EXPRESSION OF THE HYDROGENASE-ENCODING GENE FROM CLOSTRIDIUM-ACETOBUTYLICUM P262
SANTANGELO, JD
DURRE, P
WOODS, DR
[J]. MICROBIOLOGY-UK, 1995, 141 : 171 - 180
[24] Schlegel H. G., 1978, HYDROGENASES THEIR C, P15
[25] Internet connectivity
Sikorski, R
Peters, R
[J]. SCIENCE, 1998, 280 (5366) : 1102 - 1102
[26] Hydrogenase: A bacterial enzyme activating molecular hydrogen. I. The properties of the enzyme.
Stephenson, M
Stickland, LH
[J]. BIOCHEMICAL JOURNAL, 1931, 25 (01) : 205 - 214
[27] STOKKERMANS J, 1989, FEMS MICROBIOL LETT, V58, P217
[28] CRYSTAL-STRUCTURE OF THE NICKEL-IRON HYDROGENASE FROM DESULFOVIBRIO-GIGAS
VOLBEDA, A
CHARON, MH
PIRAS, C
HATCHIKIAN, EC
FREY, M
FONTECILLACAMPS, JC
[J]. NATURE, 1995, 373 (6515) : 580 - 587
[29] Structure of the [NiFe] hydrogenase active site: Evidence for biologically uncommon Fe ligands
Volbeda, A
Garcin, E
Piras, C
deLacey, AL
Fernandez, VM
Hatchikian, EC
Frey, M
FontecillaCamps, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (51) : 12989 - 12996
[30] CLONING OF THE GENE ENCODING THE HYDROGENASE FROM DESULFOVIBRIO-VULGARIS (HILDENBOROUGH) AND DETERMINATION OF THE NH2-TERMINAL SEQUENCE
VOORDOUW, G
WALKER, JE
BRENNER, S
[J]. EUROPEAN JOURNAL OF BIOCHEMISTRY, 1985, 148 (03): : 509 - 514

← 1 2 3 4 →