XAS study of a Pt-containing rod-like organometallic polymer

被引：10

作者：

Battocchio, C.

D'Acapito, F.

Smolentsev, G.

Soldatov, A. V.

Fratoddi, I.

Contini, G.

Davoli, I.

Polzonetti, G.

Mobilio, S.

机构：

[1] Care of ESRF, GILDA CRG, CNR, INFM Ogg, F-38043 Grenoble, France

[2] Rostov State Univ, Fac Phys, Rostov Na Donu 344090, Russia

[3] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy

[4] CNR, ISM, I-00133 Rome, Italy

[5] Univ Roma Tor Vergata, Dept Phys, INFM, I-00133 Rome, Italy

[6] Univ Roma Tre, Dept Phys, I-00146 Rome, Italy

[7] Univ Roma Tre, Unita INFM, INSTM, I-00146 Rome, Italy

[8] Univ Roma Tre, CISDiC, I-00146 Rome, Italy

来源：

CHEMICAL PHYSICS | 2006年 / 325卷 / 02期

关键词：

rod-like organometallic polymers; molecular structure; X-ray absorption spectroscopy; Refl-EXAFS; XANES data analysis; self assembled;

D O I：

10.1016/j.chemphys.2006.01.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular structure of organometallic polymer Pt-DEBP [-Pt-4PBu(3))(2)-C C-C12H8-C C-](n), has been investigated by X-ray absorption spectroscopy (XAS). Data collected at the Pt-L-III edge of Pt-DEBP thick films spin-deposited onto Cr/Si(111) and Au/Si(111) substrates, have been analyzed to achieve information about the geometrical arrangement of the acetylene moieties and of the tributyl phosphine groups around the transition metal. The hypothesised square planar configuration of the ligands around the transition metal has been confirmed. From the comparison between the atomic distances in the pellet reference sample and in the film samples the self-assembling behaviour of the rod-like organometallic polymer, attributed to the predominant intermolecular forces, has been confirmed. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：422 / 428

页数：7

共 29 条

[1] Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure [J].