Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle

被引：150

作者：

An, Jihyun ^{[1
]}

Fiorella, Richard P. ^{[1
]}

Geib, Steven J. ^{[1
]}

Rosi, Nathaniel L. ^{[1
]}

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 24期

关键词：

METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; COORDINATION POLYMER; HYDROGEN STORAGE; COMPLEXES; SORPTION; RECOGNITION; NUCLEOBASES; CHEMISTRY;

D O I：

10.1021/ja901869m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation and self-assembly of zinc adeninate macrocycles [Zn-6(adeninate)(6)(pyridine)(6)(dimethylcarbamate)(6)] is described. The macrocycles self-assemble through adenine-adenine hydrogen bonding interactions into a 3-D porous crystalline material that maintains its structural integrity after removal of guest molecules and coordinated pyridine molecules. By adjusting the activation temperature prior to gas adsorption measurements, the size of the pore aperture can be modulated to afford unique gas sorption properties including selective gas adsorption and CO2 sequestration.

引用

页码：8401 / +

页数：4

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